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Trapping reactive intermediates by mechanochemistry : elusive aryl N-Thiocarbamoylbenzotriazoles as bench-stable reagents

Štrukil, Vjekoslav; Gracin, Davor; Magdysyuk, Oxana V.; Dinnebier, Robert E.; Friščić, Tomislav (2015) Trapping reactive intermediates by mechanochemistry : elusive aryl N-Thiocarbamoylbenzotriazoles as bench-stable reagents. Angewandte Chemie International Edition, 54 (29). pp. 8440-8443. ISSN 1433-7851

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Abstract

Monitoring of mechanochemical thiocarbamoylation by in situ Raman spectroscopy revealed the formation of aryl N-thiocarbamoylbenzotriazoles, reactive intermediates deemed unisolable in solution. The first-time isolation and structural characterization of these elusive molecules demonstrates the ability of mechanochemistry to access otherwise unobtainable intermediates and offers a new range of masked isothiocyanate reagents.

Item Type: Article
Uncontrolled Keywords: mechanochemistry; reactive intermediates; thiocarbamoylation; thiourea
Subjects: NATURAL SCIENCES
NATURAL SCIENCES > Chemistry
Divisions: Division of Organic Chemistry and Biochemistry
Depositing User: Vjekoslav Štrukil
Date Deposited: 08 Dec 2016 15:33
Last Modified: 14 Dec 2016 16:03
URI: http://fulir.irb.hr/id/eprint/3178
DOI: 10.1002/anie.201502026

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