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The pancake bond: on the border of covalent and intermolecular

Molčanov, Krešimir; Stanić, Petra (2025) The pancake bond: on the border of covalent and intermolecular. CrystEngComm, 27 (29). pp. 4932-4940. ISSN 1466-8033

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Abstract

The two-electron multicentre (2e/mc) bond or pancake bond, a weak π-bond occurring between planar π-based organic radicals, is described and discussed. Its importance in chemistry (nature of the chemical bond) and materials science (its application in design of radical-based functional materials) is emphasized: the latest developments, concepts, and new directions of research; challenges and possible pitfalls are discussed.

Item Type: Article
Uncontrolled Keywords: multicentre bond; pancake bond; organic radicals
Subjects: NATURAL SCIENCES > Chemistry
Divisions: Division of Physical Chemistry
Depositing User: Lorena Palameta
Date Deposited: 28 Jul 2025 13:56
URI: http://fulir.irb.hr/id/eprint/9915
DOI: 10.1039/d5ce00286a

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