Extending the Hammett correlation to mechanochemical reactions

Vugrin, Leonarda; Carta, Maria; Delogu, Francesco; Halasz, Ivan (2023) Extending the Hammett correlation to mechanochemical reactions. Journal of the Chemical Society, Chemical Communications, 59 (12). pp. 1629-1632. ISSN 1359-7345

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Abstract

Using Raman in situ monitoring and mechanochemistry-specific kinetic analysis, we find a correlation between the reaction probability and the Hammett constants in a model mechanochemical reaction of imine formation, indicating that the body of knowledge developed in physical–organic chemistry could be transferable to ball milling reactions in the solid state.

Item Type:	Article
Additional Information:	Publisher: The Royal Society of Chemistry
Uncontrolled Keywords:	hammett correlation; mechanochemical reactions
Subjects:	NATURAL SCIENCES NATURAL SCIENCES > Chemistry NATURAL SCIENCES > Chemistry > Physical Chemistry
Divisions:	Division of Physical Chemistry
Depositing User:	Ivan Halasz
Date Deposited:	13 Feb 2025 11:56
URI:	http://fulir.irb.hr/id/eprint/9565
DOI:	10.1039/D2CC06487A

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