Milanović, Igor; Biliškov, Nikola (2024) Sodium amidoborane — a dead end for solid-state hydrogen storage or a gateway to advanced energy systems?. International Journal of Hydrogen Energy, 59 . pp. 282-298. ISSN 0360-3199
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Abstract
Alkali metal amidoboranes have been intensively investigated as potentially highly attractive candidates for solid-state hydrogen storage. In this family, sodium amidoborane NaNH2BH3 occupies a special place, due to its unique properties. From one side, its high hydrogen content (9.4 wt.%) and low dehydrogenation temperature (89 °C) make it very perspective in this regard. However, detailed studies revealed a number of very serious drawbacks, which consequently led to a dramatic reduction of the initial research hype, although potentially very interesting innovative aspects of its use beyond hydrogen storage have also been discovered. However, a critical insight to the entire field of metal amidoborane chemistry, especially in the technologically relevant context of solid-state hydrogen storage, is lacking. Thus, by this review, we want to fill this gap. Accordingly, this review brings a detailed and critical comparative discussion of synthesis and chemical properties of sodium amidoborane. They are considered not exclusive through technological, but also environmentally relevant optics with respect of their utilization in real-world advanced and sustainable energy systems.
| Item Type: | Article | ||||||||
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| Uncontrolled Keywords: | amidoborane; ammonia borane; hydride; hydrogen storage | ||||||||
| Subjects: | NATURAL SCIENCES > Chemistry > Physical Chemistry NATURAL SCIENCES > Chemistry > Inorganic Chemistry |
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| Divisions: | Division of Materials Chemistry | ||||||||
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| Depositing User: | Nikola Biliškov | ||||||||
| Date Deposited: | 29 Jul 2024 11:56 | ||||||||
| URI: | http://fulir.irb.hr/id/eprint/8953 | ||||||||
| DOI: | 10.1016/j.ijhydene.2024.02.003 |
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