Mechanochemical carbon–carbon bond formation that proceeds via a cocrystal intermediate

Lukin, Stipe; Tireli, Martinn; Lončarić, Ivor; Barišić, Dajana; Šket, Primož; Vrsaljko, Domagoj; di Michiel, Marco; Plavec, Janez; Užarević, Krunoslav; Halasz, Ivan (2018) Mechanochemical carbon–carbon bond formation that proceeds via a cocrystal intermediate. Chemical Communications, 54 (94). pp. 13216-13219. ISSN 1359-7345

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Official URL: http://doi.org/10.1039/C8CC07853J

Abstract

We report the first cocrystal as an intermediate in a solid-state organic reaction wherein molecules of barbituric acid and vanillin assume a favorable orientation for the subsequent Knoevenagel condensation.

Item Type:

Article

Uncontrolled Keywords:

mechanochemistry; organic synthesis; cocrystal; grinding; in situ

Subjects:

NATURAL SCIENCES > Chemistry

Divisions:

Division of Physical Chemistry
Theoretical Physics Division

Projects:

Project title	Project leader	Project code	Project type
Mehaniokemijska reaktivnost pod kontroliranim uvjetima temperature i atmosfere za čišću sintezu funkcionalnih materijala-MECHANOCONTROL	Krunoslav Užarević	UIP-2014-09-4744	HRZZ

Depositing User:

Stipe Lukin

Date Deposited:

23 Nov 2018 14:28

URI:

http://fulir.irb.hr/id/eprint/4348

DOI:

10.1039/C8CC07853J