Vapour-induced solid-state C–H bond activation for the clean synthesis of an organopalladium biothiol sensor

Monas, Andrea; Užarević, Krunoslav; Halasz, Ivan; Juribašić, Marina; Ćurić, Manda (2016) Vapour-induced solid-state C–H bond activation for the clean synthesis of an organopalladium biothiol sensor. Chemical Communications, 52 (88). pp. 12960-12963. ISSN 1359-7345

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Abstract

Room-temperature accelerated aging in the solid state has been applied for atom- and energy-efficient activation of either one or two C–H bonds of azobenzene and methyl orange by palladium(II) acetate. Organopalladium complexes are prepared in quantitative reactions without potentially harmful side products. Dicyclopalladated methyl orange is water-soluble and is a selective chromogenic biothiol sensor at physiologically-relevant micromolar concentrations in buffered aqueous media.

Item Type:	Article
Uncontrolled Keywords:	C-H activation; accelerated aging; palladium; azobenzene; biothiol sensor
Subjects:	NATURAL SCIENCES > Chemistry
Divisions:	Division of Physical Chemistry
Projects:	Project title Project leader Project code Project type Mehaniokemijska reaktivnost pod kontroliranim uvjetima temperature i atmosfere za čišću sintezu funkcionalnih materijala-MECHANOCONTROL Krunoslav Užarević UIP-09-2014-4744 HRZZ Zelena sinteza organopaladijevih foto-osjetljivih spojeva-GREENSENS UNSPECIFIED IP-09-2014-7984 HRZZ
Depositing User:	Marina Juribašić
Date Deposited:	19 Sep 2016 12:06
URI:	http://fulir.irb.hr/id/eprint/3057
DOI:	10.1039/C6CC06062E

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