Cyclic voltammetry of the second order CE mechanism at the thin mercury film covered stationary planar electrode

Lovrić, Milivoj (2013) Cyclic voltammetry of the second order CE mechanism at the thin mercury film covered stationary planar electrode. Journal of the Chilean Chemical Society, 58 (4). pp. 2191-2195. ISSN 0717-9324

Preview

PDF - Published Version - article Available under License Creative Commons Attribution. Download (426kB) | Preview

Abstract

A theoretical model of electrode reaction influenced by the kinetics of complex formation and dissociation is developed for cyclic voltammetry. It is assumed that the electro-reductions of free metal ions and the complex are reversible and totally irreversible, respectively, and that the ligand is not present in great excess. The results show that the stripping peak current and potential depend on the relative bulk concentration of ligand, particularly within the range 1 < < 3, and on the rate constant of complex formation.

Item Type:	Article
Uncontrolled Keywords:	cyclic voltammetry; metal complexes; kinetics of chemical reaction; CE mechanism
Subjects:	NATURAL SCIENCES > Chemistry
Divisions:	Division of Materials Chemistry
Projects:	Project title Project leader Project code Project type Elektroanalitička istraživanja mikrokristala i tragova otopljenih supstanci Milivoj Lovrić 098-0982904-2907 MZOS
Depositing User:	Milivoj Lovrić
Date Deposited:	14 Jul 2016 14:52
URI:	http://fulir.irb.hr/id/eprint/2948
DOI:	10.4067/S0717-97072013000400062

Actions (login required)

View Item