Ožegović, Antonija; Hobbs, Jordan; Mandle, Richard; Lesac, Andreja; Knežević, Anamarija (2024) Chiral cyanobiphenyl dimers – significance of the linking group for mesomorphic properties and helical induction. Journal of Materials Chemistry C, 12 (35). pp. 13985-13993. ISSN 2050-7526
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Abstract
Cyanobiphenyl (CB) mesogenic molecules are a focal point in liquid crystal (LC) research and applications due to their chemical stability, ease of synthesis, broad mesophase temperature range, and other advantageous properties. The introduction of chirality into LC systems offers unique optical and mechanical properties with great potential, and exploring the CB building block in chiral LC dimers presents a promising avenue for further research. In this study, we present the synthesis of chiral and racemic dimers bearing a chiral center as part of their flexible spacer and two CB moieties at the ends, i.e. the first chiral CB dimers. The investigation includes ester and amide linking groups near the chiral center to evaluate the impact of molecular flexibility on mesomorphic behavior and helical twisting power (HTP). The synthesis of racemic and enantiomerically pure dimers enabled the comparison of their mesogenic properties. Our results revealed CB dimers bearing ester linking group exhibit rich nematic polymorphism, including the rarely obtained room-temperature twist-bend nematic (NTB) phase. In contrast, the amide linking group suppresses LC properties but significantly enhances the HTP. These findings highlight the importance of intermolecular interactions and the balance of flexibility and rigidity near the chiral center in achieving desirable mesomorphic properties.
| Item Type: | Article | ||||||||||||
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| Uncontrolled Keywords: | Chirality; Helical Twisting Power; Liquid crystals; Liquid Crystalline Dimers; Room-temperature NTB phase | ||||||||||||
| Subjects: | NATURAL SCIENCES > Chemistry > Organic Chemistry | ||||||||||||
| Divisions: | Division of Organic Chemistry and Biochemistry | ||||||||||||
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| Depositing User: | Anamarija Knežević | ||||||||||||
| Date Deposited: | 14 Aug 2024 09:05 | ||||||||||||
| URI: | http://fulir.irb.hr/id/eprint/9012 | ||||||||||||
| DOI: | 10.1039/D4TC02597K |
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