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Influence of electrode radius on apparent lability of complex of amalgam forming ions

Lovrić, Milivoj; Komorsky-Lovrić, Šebojka (2014) Influence of electrode radius on apparent lability of complex of amalgam forming ions. International journal of electrochemical science, 9 (10). pp. 5549-5559. ISSN 1452-3981

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Abstract

A theory of reversible electrode reaction preceded by the reversible chemical reaction is developed for square-wave voltammetry of amalgam forming ions on spherical electrode. It is shown that the lability parameter is diminished as the radius of electrode is decreased. This is in agreement with the previous calculations and shows that the diffusion of amalgam within the spherical electrode has no influence on the apparent lability of metal complex.

Item Type: Article
Uncontrolled Keywords: amalgam; metal ions; complex; spherical electrode; voltammetry
Subjects: NATURAL SCIENCES > Chemistry > Physical Chemistry
Divisions: Division for Marine and Enviromental Research
Projects:
Project titleProject leaderProject codeProject type
Histološka, MRI i analiza genske ekspresije reorganizacijskih procesa u medijalnom (limbičkom) zidu ljudskog mozga tijekom razvitka-MEDCEREBMario VukšićIP-11-2013-7379HRZZ
Razvoj voltametrijskih metoda za karakterizaciju prirodnih antioksidansa-DVMCNAŠebojka Komorsky-LovrićIP-11-2013-2072HRZZ
Depositing User: Milivoj Lovrić
Date Deposited: 14 Jul 2016 12:51
Last Modified: 14 Jul 2016 12:51
URI: http://fulir.irb.hr/id/eprint/2958

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