Influence of electrode radius on apparent lability of complex of amalgam forming ions

Lovrić, Milivoj; Komorsky-Lovrić, Šebojka (2014) Influence of electrode radius on apparent lability of complex of amalgam forming ions. International journal of electrochemical science, 9 (10). pp. 5549-5559. ISSN 1452-3981

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Abstract

A theory of reversible electrode reaction preceded by the reversible chemical reaction is developed for square-wave voltammetry of amalgam forming ions on spherical electrode. It is shown that the lability parameter is diminished as the radius of electrode is decreased. This is in agreement with the previous calculations and shows that the diffusion of amalgam within the spherical electrode has no influence on the apparent lability of metal complex.

Item Type:	Article
Uncontrolled Keywords:	amalgam; metal ions; complex; spherical electrode; voltammetry
Subjects:	NATURAL SCIENCES > Chemistry > Physical Chemistry
Divisions:	Division for Marine and Enviromental Research
Projects:	Project title Project leader Project code Project type Histološka, MRI i analiza genske ekspresije reorganizacijskih procesa u medijalnom (limbičkom) zidu ljudskog mozga tijekom razvitka-MEDCEREB Mario Vukšić IP-11-2013-7379 HRZZ Razvoj voltametrijskih metoda za karakterizaciju prirodnih antioksidansa-DVMCNA Šebojka Komorsky-Lovrić IP-11-2013-2072 HRZZ
Depositing User:	Milivoj Lovrić
Date Deposited:	14 Jul 2016 12:51
URI:	http://fulir.irb.hr/id/eprint/2958

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