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A model of CE mechanism on spherical electrodes

Lovrić, Milivoj; Turyan, Yakov (2003) A model of CE mechanism on spherical electrodes. Croatica Chemica Acta, 76 (3). pp. 189-197. ISSN 0011-1643

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Abstract

A model of electrode reaction preceded by a first-order chemical reaction under chronoamperometric conditions on spherical electrodes has been developed. A general solution applying to all values of equilibrium constants, including very small ones, was obtained by numerical integration. Well-known analytical solutions for steady-state and near-steady-state conditions and for pure kinetic currents were shown to be special cases of the general solution. The conditions for their application are given.

Item Type: Article
Uncontrolled Keywords: CE mechanism; chronoamperometry; spherical electrodes; microelectrodes; square-wave voltammetry; microelectrode voltammetry; kinetic currents; metal-complexes; polarography; diffusion; lability; acid
Subjects: NATURAL SCIENCES > Chemistry
Divisions: Division for Marine and Enviromental Research
Projects:
Project titleProject leaderProject codeProject type
Elektroanalitička istraživanja u tekućim i krutim elektrolitimaMilivoj Lovrić0098123MZOS
Depositing User: Milivoj Lovrić
Date Deposited: 15 Nov 2013 12:24
Last Modified: 27 Feb 2014 13:11
URI: http://fulir.irb.hr/id/eprint/951

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