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Hydrogen bonding and molecular assemblies

Kojić-Prodić, Biserka; Štefanić, Zoran; Žinić, Mladen (2004) Hydrogen bonding and molecular assemblies. Croatica Chemica Acta, 77 (3). pp. 415-425. ISSN 0011-1643

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Abstract

The old concept of complementarity, connected with the process of molecular recognition represents a simple approach to understanding molecular assembling. The noncovalent interactions governing (self)assemblies are fundamental to supramolecular chemistry and crystal engineering. Among noncovalent interactions governing molecular assembling, hydrogen bonding plays the leading role. A few examples of molecular assembling relevant to life processes and (bio)nano materials reveal the importance of this phenomenon. Systematic analysis of hydrogen bonding patterns, as a function of proton donor and acceptor properties, and stereochemical parameters, including chirality, is presented for a large number of di(amino acid) and di(amino alcohol) derivatives with oxalyl, phthaloyl, and fumaroyl bridges. Particular attention will be given to the molecular topology of such hydrogen bonded assemblies in terms of crystal engineering.

Item Type: Article
Uncontrolled Keywords: complementarity principle; molecular assembling; hydrogen bonding; supramolecular assemblies; oxalyl and phthaloyl derivatives of amino acids; crystal; design; oxalamide; functionality; symmetry; patterns; gelators; solids
Subjects: NATURAL SCIENCES > Chemistry
Divisions: Division of Organic Chemistry and Biochemistry
Division of Physical Chemistry
Projects:
Project titleProject leaderProject codeProject type
Supramolekularna organizacija u gelovima, molekulsko prepoznavanje i katalizaMladen Žinić0098053MZOS
Struktura i dinamika (bio)molekulaBiserka Kojić-Prodić0098036MZOS
Depositing User: Biserka Kojić-Prodić
Date Deposited: 11 Nov 2013 12:57
Last Modified: 26 Feb 2014 13:30
URI: http://fulir.irb.hr/id/eprint/916

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