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Novel 1,4-disubstituted adamantane stereoisomers: Synthesis and spectroscopic characterization

Šafar-Cvitaš, Dunja; Savin, Branka; Mlinarić-Majerski, Kata (2004) Novel 1,4-disubstituted adamantane stereoisomers: Synthesis and spectroscopic characterization. Croatica Chemica Acta, 77 (4). pp. 619-625. ISSN 0011-1643

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Abstract

A series of new 1,4-disubstituted adamantane derivatives [e.g., 1-chloro-4-(carbethoxymethylene)adamantane (3), 1-chloro-4-(carbethoxymethyl)adamantane (4), 1-chloro-4-(2-hydroxyethyl)adamantane (5), 1-chloro-4-(2-bromoethyl)adamantane (6), 1-bromo-4-(2-bromoethyl)adamantane (7), 1-hydroxy-4-(carbethoxymethylene)adamantane (8), 1-hydroxy-4-(carbethoxy methyl)adamantane (9), 1-acetoxy-4-(carbethoxymethyl)adamantane (10),1-hydroxy-4-(2-hydroxyethyl)adamantane (11), 1-hydroxy-4-cyanoadamantane (12), 1-hydroxy-4-carboxyadamantane (13), and 1-hydroxy-4-carbmethoxyadamantane (14)] have been synthesized, and their respective syn- and anti-isomers have been separated and identified.

Item Type: Article
Uncontrolled Keywords: adamantane; 1,4-disubstituted adamantane derivative; syn-/anti-isomers; derivatives
Subjects: NATURAL SCIENCES > Chemistry
Divisions: Division of Organic Chemistry and Biochemistry
Projects:
Project titleProject leaderProject codeProject type
Sinteza, molekulska struktura i funkcija policikličkih molekulaKata Majerski0098052MZOS
Depositing User: Kata Majerski
Date Deposited: 08 Nov 2013 14:44
Last Modified: 26 Feb 2014 12:31
URI: http://fulir.irb.hr/id/eprint/912

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