Advancing mechanochemical synthesis by combining milling with different energy sources

Martinez, Valentina; Stolar, Tomislav; Karadeniz, Bahar; Brekalo, Ivana; Užarević, Krunoslav (2023) Advancing mechanochemical synthesis by combining milling with different energy sources. Nature Reviews Chemistry, 7 (1). pp. 51-65. ISSN 2397-3358

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Official URL: http://doi.org/10.1038/s41570-022-00442-1

Abstract

Owing to its efficiency and unique reactivity, mechanochemical processing of bulk solids has developed into a powerful tool for the synthesis and transformation of various classes of materials. Nevertheless, mechanochemistry is primarily based on simple techniques, such as milling in comminution devices. Recently, mechanochemical reactivity has started being combined with other energy sources commonly used in solution-based chemistry. Milling under controlled temperature, light irradiation, sound agitation or electrical impulses in newly developed experimental setups has led to reactions not achievable by conventional mechanochemical processing. This Perspective describes these unique reactivities and the advances in equipment tailored to synthetic mechanochemistry. These techniques — thermo-mechanochemistry, sono-mechanochemistry, electro-mechanochemistry and photo-mechanochemistry — represent a notable advance in modern mechanochemistry and herald a new level of solid-state reactivity: mechanochemistry 2.0.

Item Type:

Article

Uncontrolled Keywords:

mechanochemistry; perspective; combining other energy sources;

Subjects:

NATURAL SCIENCES > Physics
NATURAL SCIENCES > Chemistry

Divisions:

Division of Physical Chemistry

Projects:

Project title	Project leader	Project code	Project type
Mehanokemijske i bezotopinske strategije za sintezu funkcionalnih poroznih materijala s naprednim fizičko-kemijskim i katalitičkim svojstvima-MECHADVANCE	Krunoslav Užarević	PZS-2019-02-4129	HRZZ
Važnost mehanokemijske reaktivnosti u prebiotičkoj kemijskoj evoluciji i njezin prijenos na održivu kemijsku proizvodnju s niskim emisijama-PREBIOMECHEM	Krunoslav Užarević	IP-2020-02-4702	HRZZ

Depositing User:

Krunoslav Užarević

Date Deposited:

04 Sep 2023 09:27

URI:

http://fulir.irb.hr/id/eprint/8135

DOI:

10.1038/s41570-022-00442-1