Lovrić, Milivoj; Komorsky-Lovrić, Šebojka
(2012)
Theory of Square-wave Voltammetry of Kinetically Controlled Two-step Electrode Reactions.
Croatica Chemica Acta, 85
(4).
pp. 569-575.
ISSN 0011-1643
Abstract
An influence of electron transfer kinetics on square-wave voltammograms of two-step electrode reaction is investigated theoretically. A phenomenon of "kinetic burden" of potential inversion is described for the case of equal kinetic parameters. A linear relationship between standard rate constant and the difference between standard potentials of the second and the first charge transfers is demonstrated for the reactions with thermodynamically unstable intermediate.
Item Type: |
Article
|
Uncontrolled Keywords: |
square-wave voltammetry; kinetics of electrode reaction; two-step electrode reaction; intermediate; standard rate constant; cyclic voltammetry; comproportionation; molecules; electrochemistry; voltammograms; intermediate; polarography; reduction; transfers; mechanism |
Subjects: |
NATURAL SCIENCES > Chemistry |
Divisions: |
Division for Marine and Enviromental Research |
Projects: |
Project title | Project leader | Project code | Project type |
---|
Elektroanalitička istraživanja mikrokristala i tragova otopljenih supstanci | [26554] Milivoj Lovrić | 098-0982904-2907 | MZOS |
|
Depositing User: |
Šebojka Komorsky-Lovrić
|
Date Deposited: |
11 Oct 2013 11:00 |
URI: |
http://fulir.irb.hr/id/eprint/773 |
DOI: |
10.5562/cca2126 |
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773
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