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Controlling Orthogonal Self-Assembly through Cis-Trans Isomerization of a Non-Covalent Palladium Complex Dimer

Kokan, Zoran; Kovačević, Borislav; Štefanić, Zoran; Tzvetkova, Pavleta; Kirin, Srećko (2018) Controlling Orthogonal Self-Assembly through Cis-Trans Isomerization of a Non-Covalent Palladium Complex Dimer. Chemical Communications, 54 (17). pp. 2094-2097. ISSN 1359-7345

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The trans-configured square-planar complex of dichloropalladium and chiral monodentate phosphine ligands forms self-complementary dimers through 16 hydrogen bonded amides and π- π stacking in chlorinated solvents. The self- assembly is controled by cis-trans isomerisation of the metal center, where trans- configuration governs the dimer formation.

Item Type: Article
Additional Information: Financial support from the Croatian Science Foundation (IP-2014-09-1461) and a Croatian-German MSE-DAAD bilateral project is gratefully acknowledged. B. K. thanks the University of Zagreb Computing Centre (SRCE) for granting computational time on the ISABELLA cluster and CRO-NGI infrastructure. Z. S. thanks Dyanne Cruickshank from Rigaku, for the assistance during data collection and structure determination. P. T. thanks the Deutsche Forschungsgemeinschaft (LU 835/6-2, LU 835/13-1, instrumentation facility Pro2NMR), the HGF program BIFTM and the Fonds der Chemischen Industrie for financial support.
Uncontrolled Keywords: dichloropalladium ; chiral ; self-assembly
Subjects: NATURAL SCIENCES > Chemistry
NATURAL SCIENCES > Chemistry > Inorganic Chemistry
NATURAL SCIENCES > Chemistry > Organic Chemistry
Divisions: Division of Materials Chemistry
Division of Physical Chemistry
Project titleProject leaderProject codeProject type
Minimalni umjetni enzimi: Proširenje primjene posredne indukcije na nove supstrate i nove asimetrične reakcije-MArtEnSrećko KirinIP-2014-09-1461HRZZ
Depositing User: Srećko Kirin
Date Deposited: 21 Nov 2019 11:29
DOI: 10.1039/C7CC09537F

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