hrvatski jezikClear Cookie - decide language by browser settings

Plasmonic Nanoparticles and Island Films for Solar Energy Harvesting: A Comparative Study of Cu, Al, Ag and Au Performance

Fabijanić, Ivana; Janicki, Vesna; Ferré- Borrull, Josep; Bubaš, Matej; Blažek Bregović, Vesna; Marsal, Lluis F.; Sancho- Parramon, Jordi (2019) Plasmonic Nanoparticles and Island Films for Solar Energy Harvesting: A Comparative Study of Cu, Al, Ag and Au Performance. Coatings, 9 (6). pp. 1-15. ISSN 2079-6412

PDF - Published Version - article
Available under License Creative Commons Attribution.

Download (5MB) | Preview


Alternative materials that can potentially replace Au and Ag in plasmonics and broaden its application potential have been actively investigated over the last decade. Cu and Al have been usually overlooked as plasmonic material candidates because they are prone to oxidisation. In this work the plasmonic performance of Cu and Al is investigated using numerical simulations of different nanostructures (spheres, cubes, rods and particle dimers) and taking into account the presence of oxidisation. It is shown that geometry can play a dominant role over material properties and the performance of Cu and Al becomes comparable to that of Ag and Au for systems of non-spherical particles and strong electromagnetic coupling among particles. This observation is experimentally confirmed by the fabrication and characterisation of Cu and Al metal island films. Optical characterisation of the samples reveals a comparable performance of these metals to that obtained for Ag and Au and suggests that Cu and Al metal island films can offer an efficient low-cost platform for solar energy harvesting, as shown in water vapour generation proof of concept experiments.

Item Type: Article
Uncontrolled Keywords: metal island films ; copper ; aluminium ; ellipsometry ; electrodynamics simulations ; solar energy harvesting
Subjects: NATURAL SCIENCES > Physics
Divisions: Division of Materials Physics
Project titleProject leaderProject codeProject type
Plazmonički alternativni materijali za konverziju solarne energije-PAMSECJordi Sancho-ParramonPKP-2016-06-4469HRZZ
Depositing User: Ivana Fabijanić
Date Deposited: 12 Sep 2019 06:39
DOI: 10.3390/coatings9060382

Actions (login required)

View Item View Item


Downloads per month over past year

Increase Font
Decrease Font
Dyslexic Font