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Theory of square-wave voltammetry of two-step electrode reaction using an inverse scan direction

Lovrić, Milivoj; Komorsky-Lovrić, Šebojka (2011) Theory of square-wave voltammetry of two-step electrode reaction using an inverse scan direction. International Journal of Electrochemistry, 2011 . ISSN 2090-3529

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Abstract

A theory of square-wave voltammetry of two-step electrode reaction with kinetically controlled electron transfers is developed and a special case of thermodynamically unstable intermediate is analyzed. If the first reaction step is reversible and the second one is quasireversible, the response splits into two peaks if the scan direction is inverted. The separation of these peaks increases with frequency.

Item Type: Article
Uncontrolled Keywords: Square-wave voltammetry ; two-step electrode reaction ; theory of quasireversible EE mechanism
Subjects: NATURAL SCIENCES > Chemistry
Divisions: Division of Materials Chemistry
Projects:
Project titleProject leaderProject codeProject type
Elektroanalitička istraživanja mikrokristala i tragova otopljenih supstanci-Milivoj Lovrić098-0982904-2907MZOS
Depositing User: Milivoj Lovrić
Date Deposited: 30 Aug 2018 06:55
Last Modified: 30 Aug 2018 06:58
URI: http://fulir.irb.hr/id/eprint/4150
DOI: 10.4061/2011/538341

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