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Simulation of influence of variable diffusion coefficient in cyclic voltammetry

Lovrić, Milivoj; Komorsky-Lovrić, Šebojka (2015) Simulation of influence of variable diffusion coefficient in cyclic voltammetry. Analytical and bioanalytical electrochemistry, 7 (2). pp. 220-229. ISSN 2008-4226

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Abstract

A model of electrode reaction of solid compound that includes an insertion of cations from the solution is developed and the influence of concentration-dependent diffusion coefficient in cyclic voltammetry is investigated theoretically. Generally, the form of response does not change significantly, but in some cases the cathodic peak may split in two.

Item Type: Article
Uncontrolled Keywords: Cyclic voltammetry; diffusion coefficient; solid-state electrode reactions; insertion compounds
Subjects: NATURAL SCIENCES > Chemistry > Physical Chemistry
Divisions: Division of Materials Chemistry
Depositing User: Milivoj Lovrić
Date Deposited: 04 Jul 2016 14:45
Last Modified: 04 Jul 2016 14:45
URI: http://fulir.irb.hr/id/eprint/2936

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