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UV photoelectron spectroscopy and outer valence electronic structure of dihalobenzenes

Novak, Igor; Klasinc, Leo; Šket, Boris; Chong, Delano P.; McGlynn, Sean P. (2014) UV photoelectron spectroscopy and outer valence electronic structure of dihalobenzenes. Croatica Chemica Acta, 87 (4). pp. 495-499. ISSN 0011-1643

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Abstract

The electronic structures of nine dihalobenzenes (C6H4FX; X = Cl, Br, I) have been studied by UV photoelectron spectroscopy (UPS) and assigned by comparison with the reported spectra of monoha-lobenzenes (C6H5X; X = Cl, Br, I). and quantum chemical calculations. Our results show that the fluorine substituent modifies energies of π- and halogen lone pair orbitals to a significant degree depending on its location (topology). We also demonstrate that the inductive effect of fluorine atom on the benzene ring can be readily observed and interpreted.

Item Type: Article
Uncontrolled Keywords: halobenzenes; inductive effect; resonance effect
Subjects: NATURAL SCIENCES > Chemistry
Divisions: Division of Physical Chemistry
Depositing User: Sofija Konjević
Date Deposited: 17 Apr 2015 13:57
Last Modified: 11 May 2016 11:50
URI: http://fulir.irb.hr/id/eprint/1716
DOI: 10.5562/cca2438

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