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Regioselective transesterifications of cyclohexanone derivatives containing beta-keto and malonic ester moieties

Makarević, Janja; Žinić, Mladen (1998) Regioselective transesterifications of cyclohexanone derivatives containing beta-keto and malonic ester moieties. Croatica Chemica Acta, 71 (3). pp. 817-825. ISSN 0011-1643

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Abstract

The cyclohexanone derivatives 1-6 containing beta-ketoester and alpha-disubstituted malonic ester moieties in the same molecule were found to undergo regioselective transesterifications with benzyl alcohol giving exclusively beta-keto benzyl esters. On the contrary, the acyclic derivatives 9, 10 containing beta-ketoester and alpha-monosubstituted malonic ester groups gave mixtures of transesterified products under the same reaction conditions.

Item Type: Article
Uncontrolled Keywords: acid hida; reduction
Subjects: NATURAL SCIENCES > Chemistry
Divisions: Division of Organic Chemistry and Biochemistry
Projects:
Project titleProject leaderProject codeProject type
Projektiranje i sinteza supramolekularnih sustavaMladen Žinić00980703MZOS
Depositing User: Mladen Žinić
Date Deposited: 27 Nov 2013 14:10
Last Modified: 07 Mar 2014 09:06
URI: http://fulir.irb.hr/id/eprint/1149

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