Regioselective transesterifications of cyclohexanone derivatives containing beta-keto and malonic ester moieties

Makarević, Janja; Žinić, Mladen (1998) Regioselective transesterifications of cyclohexanone derivatives containing beta-keto and malonic ester moieties. Croatica Chemica Acta, 71 (3). pp. 817-825. ISSN 0011-1643

PDF - Published Version Download (93kB)

Abstract

The cyclohexanone derivatives 1-6 containing beta-ketoester and alpha-disubstituted malonic ester moieties in the same molecule were found to undergo regioselective transesterifications with benzyl alcohol giving exclusively beta-keto benzyl esters. On the contrary, the acyclic derivatives 9, 10 containing beta-ketoester and alpha-monosubstituted malonic ester groups gave mixtures of transesterified products under the same reaction conditions.

Item Type:	Article
Uncontrolled Keywords:	acid hida; reduction
Subjects:	NATURAL SCIENCES > Chemistry
Divisions:	Division of Organic Chemistry and Biochemistry
Projects:	Project title Project leader Project code Project type Projektiranje i sinteza supramolekularnih sustava Mladen Žinić 00980703 MZOS
Depositing User:	Mladen Žinić
Date Deposited:	27 Nov 2013 14:10
URI:	http://fulir.irb.hr/id/eprint/1149

Actions (login required)

View Item