Pinacho, Pablo; Loru, Donatella; Šumanovac, Tatjana; Šekutor, Marina; Schnell, Melanie (2023) Increasing Complexity in Adamantyl Thioethers Characterized by Rotational Spectroscopy. ChemPhysChem, 24 (23). ISSN 1439-4235
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Abstract
We report on the synthesis and characterization using high-resolution rotational spectroscopy of three bulky thioethers that feature an adamantyl group connected to a sulfur atom. Detailed experimental and theoretical structures are provided and compared with the 1,1′-diadamantyl ether. In addition, we expand on previous findings concerning microsolvation of adamantyl derivatives by investigating the cluster formation between these thioethers and a water molecule. The investigation of such clusters provides valuable insights into the sulfur-centered hydrogen bonding in thioethers with increasing size and steric repulsion.
| Item Type: | Article | ||||||||
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| Uncontrolled Keywords: | thioether ; sulfur centered hydrogen bond ; adamantyl derivatives ; non-covalent interactions ; rotational spectroscopy | ||||||||
| Subjects: | NATURAL SCIENCES > Chemistry > Physical Chemistry NATURAL SCIENCES > Chemistry > Theoretical Chemistry NATURAL SCIENCES > Chemistry > Organic Chemistry |
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| Divisions: | Division of Organic Chemistry and Biochemistry | ||||||||
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| Depositing User: | Marina Šekutor | ||||||||
| Date Deposited: | 18 Dec 2025 13:29 | ||||||||
| URI: | http://fulir.irb.hr/id/eprint/10521 | ||||||||
| DOI: | 10.1002/cphc.202300561 |
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