Abrupt change from moderate positive to colossal negative thermal expansion caused by imidazolate composite formation

Burazer, Sanja; Horák, Lukáš; Filinchuk, Yaroslav; Černý, Radovan; Popović, Jasminka (2022) Abrupt change from moderate positive to colossal negative thermal expansion caused by imidazolate composite formation. Journal of Materials Science, 57 (25). pp. 11563-11581. ISSN 0022-2461

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Abstract

This work describes temperature-induced crystallization processes and reaction mechanisms occurring in the borohydride-imidazolate system. In the course of thermal evolution, crystal structures of two novel bimetallic imidazolates AMnIm(3) (A = Na, K) were solved using synchrotron radiation powder diffraction data. Both the alkali metal cation and the Mn cations exhibit distorted octahedral coordination while each imidazolate is surrounded by two alkali metal and two manganese atoms. Extensive study of the thermal expansion behaviour revealed that the expansion of the bimetallic imidazolates does not proceed uniformly over the entire temperature range but rather abruptly changes from a colossal negative to a moderate positive volume expansion. Such behaviour is caused by the coherent intergrowth of the coexisting phases which form a composite, a positive lattice mismatch and a tensile strain during the coexistence of NaMIm(3) (M = Mg and Mn) and NaIm or HT-NaIm. Such coherent coalescence of two materials opens the possibility for targeted design of zero thermal expansion materials.

Item Type:	Article
Uncontrolled Keywords:	negative thermal expansion ; structure determination from X-ray powder diffraction ; synchrotron radiation ; coherent intergrowth ; microstructure
Subjects:	NATURAL SCIENCES NATURAL SCIENCES > Chemistry
Divisions:	Division of Materials Physics
Depositing User:	Kristina Ciglar
Date Deposited:	10 Jul 2026 13:32
URI:	https://fulir.irb.hr:/id/eprint/12047
DOI:	10.1007/s10853-022-07360-z

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