A model of CE mechanism on spherical electrodes

Lovrić, Milivoj; Turyan, Yakov (2003) A model of CE mechanism on spherical electrodes. Croatica Chemica Acta, 76 (3). pp. 189-197. ISSN 0011-1643

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Abstract

A model of electrode reaction preceded by a first-order chemical reaction under chronoamperometric conditions on spherical electrodes has been developed. A general solution applying to all values of equilibrium constants, including very small ones, was obtained by numerical integration. Well-known analytical solutions for steady-state and near-steady-state conditions and for pure kinetic currents were shown to be special cases of the general solution. The conditions for their application are given.

Item Type:	Article
Uncontrolled Keywords:	CE mechanism; chronoamperometry; spherical electrodes; microelectrodes; square-wave voltammetry; microelectrode voltammetry; kinetic currents; metal-complexes; polarography; diffusion; lability; acid
Subjects:	NATURAL SCIENCES > Chemistry
Divisions:	Division for Marine and Enviromental Research
Projects:	Project title Project leader Project code Project type Elektroanalitička istraživanja u tekućim i krutim elektrolitima Milivoj Lovrić 0098123 MZOS
Depositing User:	Milivoj Lovrić
Date Deposited:	15 Nov 2013 12:24
URI:	http://fulir.irb.hr/id/eprint/951

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