Gas phase ligation of U+. Comparison of pyrene, phenanthridine and phenanthrene as ligands

Kazazić, Saša; Kazazić, Snježana; Klasinc, Leo; Rožman, Marko; Srzić, Dunja (2006) Gas phase ligation of U+. Comparison of pyrene, phenanthridine and phenanthrene as ligands. Croatica Chemica Acta, 79 (1). pp. 125-128. ISSN 0011-1643

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Abstract

Ligation of U+ with phenanthrene in an FT ICR MS instrument is compared with previous results on U+ with pyrene and phenanthridine. All investigated processes compete with U+ oxidation by water and oxygen traces in the instrument. The comparison indicates that oxidation preferentially involves dehydrogenated ligation products.

Item Type:	Article
Uncontrolled Keywords:	ligation reaction; gas phase kinetics; uranium monocation; pyrene; phenanthridine; phenanthrene; FT ICR MS; transform mass-spectrometry; ions; benzene; complexes; FTMS; NB+; FE+
Subjects:	NATURAL SCIENCES > Chemistry
Divisions:	Division of Physical Chemistry
Projects:	Project title Project leader Project code Project type Reaktivnost i reakcijski mehanizmi Dunja Srzić 0098032 MZOS
Depositing User:	Leo Klasinc
Date Deposited:	30 Oct 2013 09:31
URI:	http://fulir.irb.hr/id/eprint/869

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