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Reverse scan as a source of information in square wave voltammetry

Zelić, Marina (2006) Reverse scan as a source of information in square wave voltammetry. Croatica Chemica Acta, 79 (1). pp. 49-55. ISSN 0011-1643

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Abstract

Under the influence of recently published articles, reverse scans in square wave voltammetry were applied in a study of Eu3+/EU2+ redox system at increasing concentrations of several electrolytes, and gradually changing frequency or step potential. The electrode response is highly affected by all these factors and two peaks can appear though only one electroactive species is present in the solution and one electron included in the process, whereas adsorption of the reactant or product is not pronounced. Scanning in both directions appears as a potential tool for kinetic studies of the electrode processes although in the studied system its practical application meets various problems.

Item Type: Article
Uncontrolled Keywords: square wave voltammetry; reverse scan; electrode kinetics; europium; electrolyte; kinetics; deconvolution; dependence; adsorption; couple; media
Subjects: NATURAL SCIENCES > Chemistry
Divisions: Division for Marine and Enviromental Research
Projects:
Project titleProject leaderProject codeProject type
Elektroanalitička istraživanja u tekućim i krutim elektrolitimaMilivoj Lovrić0098123MZOS
Depositing User: Marina Zelić
Date Deposited: 29 Oct 2013 10:38
Last Modified: 14 Feb 2014 15:25
URI: http://fulir.irb.hr/id/eprint/862

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