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Scope and limitations of sodium and potassium trimethylsilanolate as reagents for conversion of esters to carboxylic acids

Lovrić, Marija; Cepanec, Ivica; Litvić, Mladen; Bartolinčić, Anamarija; Vinković, Vladimir (2007) Scope and limitations of sodium and potassium trimethylsilanolate as reagents for conversion of esters to carboxylic acids. Croatica Chemica Acta, 80 (1). pp. 109-115. ISSN 0011-1643

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Abstract

Sodium or potassium trimethylsilanolate act as versatile and very powerful reagents for conversion of a wide variety of esters to carboxylic acids. The reactions were performed in tetrahydrofuran under mild reaction conditions with high to quantitative yields.

Item Type: Article
Uncontrolled Keywords: esters; carboxylic acids; sodium trimethylsilanolate; potassium trimethylsilanolate; nucleophilic substitution; phase-transfer catalysis; hindered esters; hydrolysis; water; iodide
Subjects: NATURAL SCIENCES > Chemistry
Divisions: Division of Organic Chemistry and Biochemistry
Projects:
Project titleProject leaderProject codeProject type
Kiralni organski materijali – sintetska, strukturna i funkcionalna istraživanja[71214] Vladimir Vinković098-0982904-2910MZOS
Depositing User: Vladimir Vinković
Date Deposited: 28 Oct 2013 10:41
Last Modified: 14 Feb 2014 15:13
URI: http://fulir.irb.hr/id/eprint/851

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