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Photochemistry of N-alkyl and N-aryl Substituted Phthalimides: H-Abstractions, Single Elelctron Transfer and Cycloadditions

Horvat, Margareta; Mlinarić-Majerski, Kata; Basarić, Nikola (2010) Photochemistry of N-alkyl and N-aryl Substituted Phthalimides: H-Abstractions, Single Elelctron Transfer and Cycloadditions. Croatica Chemica Acta, 83 (2). pp. 179-188. ISSN 0011-1643

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Abstract

The phthalimide chromophore shows a broad spectrum of intra- and intermolecular photochemical transformations. Photoreactions of phthalimide derivatives can be classified in three main groups: H-abstraction, cycloaddition and single electron transfer. The photoproducts are aza-heterocycles, useful synthons in the synthesis of more complex heterocyclic and natural products. The aim of this review is to provide an overview of the synthetic applicability of these processes, as well as to point out the parameters that influence the photochemical reactivity of phthalimides.

Item Type: Article
Uncontrolled Keywords: phthalimides; photochemistry; H-abstractions; photoinduced electron transfer; cycloadditions; ylide-forming photoreactions; alpha-amino-acids; electron-transfer; photocyclization reactions; geometric requirements; phthaloyl derivatives; flash-photolysis; aqueous-solution; solid-state; ii reaction
Subjects: NATURAL SCIENCES > Chemistry
Divisions: Division of Organic Chemistry and Biochemistry
Projects:
Project titleProject leaderProject codeProject type
Kavezasti spojevi: ugradbene jedinice u molekularnim sustavima[27342] Kata Majerski098-0982933-2911MZOS
Depositing User: Nikola Basarić
Date Deposited: 17 Oct 2013 07:55
Last Modified: 10 Feb 2014 09:47
URI: http://fulir.irb.hr/id/eprint/802

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