Ardila‐Fierro, Karen J.; Vugrin, Leonarda; Halasz, Ivan; Palčić, Ana; Hernández, José G. (2022) Mechanochemical Bromination of Naphthalene Catalyzed by Zeolites: From Small Scale to Continuous Synthesis. Chemistry methods, 2 (12). ISSN 2628-9725
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Abstract
Catalyzed reactions of organic substrates that operate continuously by extrusion techniques are rare. In this study, we developed a mechanochemical bromination of unactivated naphthalene (1) with 1, 3-dibromo-5, 5- dimethylhydantoin (DBDMH) catalyzed by zeolites in a ball mill. The use of DBDMH enabled the atom economy of the reaction to be superior compared to the other brominating agents evaluated. Among the zeolites tested, a FAU-type zeolite demonstrated high catalytic activity and recyclability. The success of the bromination route on a small scale enabled the development of a continuous catalyzed bromination of 1 by twin- screw extrusion.
| Item Type: | Article | ||||||||||||
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| Uncontrolled Keywords: | mechanochemistry ; bromination ; zeolite ; scale-up ; extrusion | ||||||||||||
| Subjects: | NATURAL SCIENCES > Chemistry | ||||||||||||
| Divisions: | Division of Materials Chemistry Division of Physical Chemistry |
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| Depositing User: | Sofija Konjević | ||||||||||||
| Date Deposited: | 16 Dec 2022 09:46 | ||||||||||||
| URI: | http://fulir.irb.hr/id/eprint/7744 | ||||||||||||
| DOI: | 10.1002/cmtd.202200035 |
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