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Mixed Spacer Cation Stabilization of Blue‐Emitting n = 2 Ruddlesden–Popper Organic–Inorganic Halide Perovskite Films

Leung, Tik Lun; Tam, Ho Won; Liu, Fangzhou; Lin, Jingyang; Ng, Alan Man Ching; Chan, Wai Kin; Chen, Wei; He, Zhubing; Lončarić, Ivor; Grisanti, Luca; Ma, Chao; Wong, Kam Sing; Lau, Ying Suet; Zhu, Furong; Skoko, Željko; Popović, Jasminka; Djurišić, Aleksandra B. (2020) Mixed Spacer Cation Stabilization of Blue‐Emitting n = 2 Ruddlesden–Popper Organic–Inorganic Halide Perovskite Films. Advanced Optical Materials, 8 (4). ISSN 2195-1071

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Ruddlesden–Popper halide perovskite (RPP) materials are of significant interest for light-emitting devices since their emission wavelength can be controlled by tuning the number of layers n, resulting in improved spectral stability compared to mixed halide devices. However, RPP films typically contain phases with different n, and the low n phases tend to be unstable upon exposure to humidity, irradiation, and/or elevated temperature which hinders the achievement of pure blue emission from n = 2 films. In this work, two spacer cations are used to form an RPP film with mixed cation bilayer and high n = 2 phase purity, improved stability, and brighter light emission compared to a single spacer cation RPP. The stabilization of n = 2 phase is attributed to favorable formation energy, reduced strain, and reduced electron–phonon coupling compared to the RPP films with only one type of spacer cation. Using this approach, pure blue light-emitting diodes (LEDs) with Commission Internationale de l'éclairage (CIE) coordinates of (0.156, 0.088) and excellent spectral stability are achieved.

Item Type: Article
Uncontrolled Keywords: perovskite LED ; density functional theory
Subjects: NATURAL SCIENCES > Physics
NATURAL SCIENCES > Physics > Condensed Matter Physics
Divisions: Theoretical Physics Division
Project titleProject leaderProject codeProject type
Sinergijom do uspjeha: RBI-T-WINNING i ESIF udruženi u jačanju izvrsnosti Zavoda za teorijsku fiziku Instituta Ruđer Bošković-RBI-TWINN-SINBlaženka MelićKK.
Depositing User: Ivor Lončarić
Date Deposited: 22 Nov 2021 10:03
DOI: 10.1002/adom.201901679

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