Bis‐[3]Ferrocenophanes with Central >E−E’< Bonds (E, E’=P, SiH): Preparation, Properties, and Thermal Activation

Isenberg, Stefan; Weller, Stefan; Kargin, Denis; Valić, Srećko; Schwederski, Brigitte; Kelemen, Zsolt; Bruhn, Clemens; Krekić, Kristijan; Maurer, Martin; Feil, Christoph M.; Nieger, Martin; Gudat, Dietrich; Nyulászi, László; Pietschnig, Rudolf (2019) Bis‐[3]Ferrocenophanes with Central >E−E’< Bonds (E, E’=P, SiH): Preparation, Properties, and Thermal Activation. ChemistryOpen, 8 (10). pp. 1235-1243. ISSN 2191-1363

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Abstract

A series of bis-[3]ferrocenophanes of the general type Fe(C5H4E')2E-E(E'C5H4)2Fe (E=P, SiH and E'=PtBu, NneoPentyl, NSi(CH3)3) with an isolobal molecular framework have been prepared and characterized by heteronuclear NMR spectroscopy and X-ray crystallography. The thermal dissociation behavior with respect to homolytic fission of the central bond generating phosphorus centered radicals was investigated using EPR spectroscopy and quantum chemical calculations.

Item Type:	Article
Uncontrolled Keywords:	ferrocene ; homolytic bond cleavage ; phosphorus ; radicals ; thermolysis
Subjects:	NATURAL SCIENCES > Chemistry
Divisions:	Division of Physical Chemistry
Projects:	Project title Project leader Project code Project type Studija važnosti spinskih međudjelovanja kao osnova za nove pristupe u istraživanju materijala-SPES Marina Ilakovac Kveder IP-2018-01-3168 HRZZ
Depositing User:	Srećko Valić
Date Deposited:	05 Jun 2020 09:12
URI:	http://fulir.irb.hr/id/eprint/5821
DOI:	10.1002/open.201900182

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