Green and rapid mechanosynthesis of high-porosity NU- and UiO-type metal–organic frameworks

Fidelli, Athena M.; Karadeniz, Bahar; Howarth, Ashlee J.; Huskić, Igor; Germann, Luzia S.; Halasz, Ivan; Etter, Martin; Moon, Su-Young; Dinnebier, Robert E.; Stilinović, Vladimir; Farha, Omar K.; Friščić, Tomislav; Užarević, Krunoslav (2018) Green and rapid mechanosynthesis of high-porosity NU- and UiO-type metal–organic frameworks. Chemical Communications, 54 (51). pp. 6999-7002. ISSN 1359-7345

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Official URL: http://doi.org/10.1039/C8CC03189D

Abstract

The use of a dodecanuclear zirconium acetate cluster as a precursor enables the rapid, clean mechanochemical synthesis of high-microporosity metal–organic frameworks NU-901 and UiO-67, with surface areas up to 2250 m2 g−1. Real-time X-ray diffraction monitoring reveals that mechanochemical reactions involving the conventional hexanuclear zirconium methacrylate precursor are hindered by the formation of an inert intermediate, which does not appear when using the dodecanuclear acetate cluster as a reactant.

Item Type:

Article

Additional Information:

This work has been supported by the Ministry of Environment and Energy, Ministry of Science and Education, Environmental Protection and Energy Efficiency Fund of the Republic of Croatia and the Croatian Science Foundation project "New materials for energy storage''. We acknowledge the financial support from the Croatian Science foundation (Grant No. 4744) and the grant to IH from the Adris foundation. TF acknowledges the financial support of the NSERC Discovery Grant (RGPIN-2017-06467) and the NSERC E. W. R. Steacie Memorial Fellowship (SMFSU 507347-17). O. K. F. gratefully acknowledges support from the Defense Threat Reduction Agency (HDTRA1-18-1-0003).

Uncontrolled Keywords:

Mechanochemistry; MOFs; Zirconium MOFs; UiO-67; NU-901; Green Chemistry

Subjects:

NATURAL SCIENCES > Chemistry

Divisions:

Division of Physical Chemistry

Projects:

Project title	Project leader	Project code	Project type
Mehaniokemijska reaktivnost pod kontroliranim uvjetima temperature i atmosfere za čišću sintezu funkcionalnih materijala-MECHANOCONTROL	Krunoslav Užarević	UIP-2014-09-4744	HRZZ

Depositing User:

Krunoslav Užarević

Date Deposited:

28 Nov 2019 14:11

URI:

http://fulir.irb.hr/id/eprint/5168

DOI:

10.1039/C8CC03189D