Kokan, Zoran; Kovačević, Borislav; Štefanić, Zoran; Tzvetkova, Pavleta; Kirin, Srećko (2018) Controlling Orthogonal Self-Assembly through Cis-Trans Isomerization of a Non-Covalent Palladium Complex Dimer. Chemical Communications, 54 (17). pp. 2094-2097. ISSN 1359-7345
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Official URL: http://dx.doi.org/10.1039/C7CC09537F
Abstract
The trans-configured square-planar complex of dichloropalladium and chiral monodentate phosphine ligands forms self-complementary dimers through 16 hydrogen bonded amides and π- π stacking in chlorinated solvents. The self- assembly is controled by cis-trans isomerisation of the metal center, where trans- configuration governs the dimer formation.
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| Additional Information: | Financial support from the Croatian Science Foundation (IP-2014-09-1461) and a Croatian-German MSE-DAAD bilateral project is gratefully acknowledged. B. K. thanks the University of Zagreb Computing Centre (SRCE) for granting computational time on the ISABELLA cluster and CRO-NGI infrastructure. Z. S. thanks Dyanne Cruickshank from Rigaku, for the assistance during data collection and structure determination. P. T. thanks the Deutsche Forschungsgemeinschaft (LU 835/6-2, LU 835/13-1, instrumentation facility Pro2NMR), the HGF program BIFTM and the Fonds der Chemischen Industrie for financial support. | ||||||||
| Uncontrolled Keywords: | dichloropalladium ; chiral ; self-assembly | ||||||||
| Subjects: | NATURAL SCIENCES > Chemistry NATURAL SCIENCES > Chemistry > Inorganic Chemistry NATURAL SCIENCES > Chemistry > Organic Chemistry |
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| Divisions: | Division of Materials Chemistry Division of Physical Chemistry |
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| Depositing User: | Srećko Kirin | ||||||||
| Date Deposited: | 21 Nov 2019 11:29 | ||||||||
| URI: | http://fulir.irb.hr/id/eprint/5107 | ||||||||
| DOI: | 10.1039/C7CC09537F |
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