Alkali salts of nitranilic and cyanochloranilic acids

Milašinović, Valentina; Molčanov, Krešimir (2018) Alkali salts of nitranilic and cyanochloranilic acids. Croatica chemica acta, 91 (2). pp. 177-186. ISSN 0011-1643

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Abstract

Series of novel alkali salts of nitranilic acid (3, 6-dinitro-2, 5-dihydroxyquinone) and cyanochloranilic acid (3-cyano-6-chloro-2, 5-dihydroxyquinone), and also of neutral cyanochloranilic acid dihydrate, were prepared and their structures were studied. The nitranilate dianion revealed a considerable conformational flexibility of nitro groups. Steric and inductive effects exerted by different substituents (nitro, cyano and chloro) and their influence on molecular geometry and crystal packing are discussed.

Item Type:	Article
Uncontrolled Keywords:	nitranilic acid, cyanochloranilic acid, quinone, crystal structure
Subjects:	NATURAL SCIENCES > Chemistry
Divisions:	Division of Physical Chemistry
Projects:	Project title Project leader Project code Project type Novi metal-organsi sustavi s oksalatnim i kinoidnim ligandima s podešenim svojstvima pogodnim za primjenu-NMOSBOQLWTPSFP Krešimir Molčanov IP-2014-09-4079 HRZZ
Depositing User:	Krešimir Molčanov
Date Deposited:	20 Dec 2018 08:48
URI:	https://fulir.irb.hr:/id/eprint/4384
DOI:	10.5562/cca3333

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