Alkali salts of nitranilic and cyanochloranilic acids

Milašinović, Valentina; Molčanov, Krešimir (2018) Alkali salts of nitranilic and cyanochloranilic acids. Croatica chemica acta, 91 (2). pp. 177-186. ISSN 0011-1643

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Official URL: https://hrcak.srce.hr/201072

Abstract

Series of novel alkali salts of nitranilic acid (3, 6-dinitro-2, 5-dihydroxyquinone) and cyanochloranilic acid (3-cyano-6-chloro-2, 5-dihydroxyquinone), and also of neutral cyanochloranilic acid dihydrate, were prepared and their structures were studied. The nitranilate dianion revealed a considerable conformational flexibility of nitro groups. Steric and inductive effects exerted by different substituents (nitro, cyano and chloro) and their influence on molecular geometry and crystal packing are discussed.

Item Type:

Article

Uncontrolled Keywords:

nitranilic acid, cyanochloranilic acid, quinone, crystal structure

Subjects:

NATURAL SCIENCES > Chemistry

Divisions:

Division of Physical Chemistry

Projects:

Project title	Project leader	Project code	Project type
Novi metal-organsi sustavi s oksalatnim i kinoidnim ligandima s podešenim svojstvima pogodnim za primjenu-NMOSBOQLWTPSFP	Krešimir Molčanov	IP-2014-09-4079	HRZZ

Depositing User:

Krešimir Molčanov

Date Deposited:

20 Dec 2018 08:48

URI:

http://fulir.irb.hr/id/eprint/4384

DOI:

10.5562/cca3333