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Metal-Induced Supramolecular Chirality Inversion of Small Self-Assembled Molecules in Solution

Kokan, Zoran; Perić, Berislav; Vazdar, Mario; Marinić, Željko; Vikić-Topić, Dražen; Meštrović, Ernest; Kirin, Srećko (2017) Metal-Induced Supramolecular Chirality Inversion of Small Self-Assembled Molecules in Solution. Chemical Communications, 53 (12). pp. 1945-1948. ISSN 1359-7345

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Abstract

Non-covalent self-assembled chiral alanyl aminopyridine ligand exhibits supramolecular chirality in solution, independent of the organic solvent used. The supramolecular chirality of the assemblies is completely inverted by complexation to zinc ions. Up to now, such supramolecular metal-ligand system has not been reported in the literature.

Item Type: Article
Uncontrolled Keywords: amino acids; chirality; secondary structures; Zn(II) complexes
Subjects: NATURAL SCIENCES > Chemistry
Divisions: Division of Materials Chemistry
Division of Organic Chemistry and Biochemistry
NMR Center
Projects:
Project titleProject leaderProject codeProject type
Minimalni umjetni enzimi: Proširenje primjene posredne indukcije na nove supstrate i nove asimetrične reakcije-MArtEnSrećko KirinIP-2014-09-1461HRZZ
Depositing User: Srećko Kirin
Date Deposited: 20 Nov 2018 13:31
Last Modified: 21 Nov 2018 10:00
URI: http://fulir.irb.hr/id/eprint/4321
DOI: 10.1039/c6cc09203a

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