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Photothermal Reactions of Nitrosobenzene and Halonitrosobenzenes in Solid-state

Knežević, Anamarija; Medančić, Tina; Milovac, Srđan; Biljan, Ivana; Halasz, Ivan; Vančik, Hrvoj (2011) Photothermal Reactions of Nitrosobenzene and Halonitrosobenzenes in Solid-state. Croatica Chemica Acta, 84 (1). pp. 21-24. ISSN 0011-1643

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Photothermal reactions of nitrosobenzene, m-chloronitrosobenzene, and p-chloronitrosobenzene were studied in solid-state by IR spectroscopy at low temperatures and by X-ray powder diffraction. It was found for the first time that photothermal cycle (photolytic dissociation followed by thermal dimerization) could successively be performed also with Z-configured nitrosobenzene. Halonitrosobenzenes with E-configuration afforded different photo behavior depending on the position of halogen atom on the benzene ring: while m-halonitrosobenzenes do not dissociate under UV irradiation, p-chloronitrosobenzene, as well as previously studied p-bromonitrosobenzene photolyses very efficiently with recovering of the original crystal phase. Kinetics of thermal dimerization was measured in solid-state, and it was found that the reaction phase transformation occur as a two-dimensional growth through the crystal.

Item Type: Article
Uncontrolled Keywords: nitrosobenzenes; photothermal reactions; solid-state
Subjects: NATURAL SCIENCES > Chemistry
Divisions: Division of Organic Chemistry and Biochemistry
Project titleProject leaderProject codeProject type
Reakcije organskih spojeva u čvrstom stanju: mehanizmi i supramolekulski inženje-Hrvoj Vančik119-1191342-1334MZOS
Depositing User: Anamarija Knežević
Date Deposited: 25 Oct 2017 11:22
DOI: 10.5562/cca1714

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