Štrukil, Vjekoslav; Gracin, Davor; Magdysyuk, Oxana V.; Dinnebier, Robert E.; Friščić, Tomislav (2015) Trapping reactive intermediates by mechanochemistry : elusive aryl N-Thiocarbamoylbenzotriazoles as bench-stable reagents. Angewandte Chemie International Edition, 54 (29). pp. 8440-8443. ISSN 1433-7851
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Abstract
Monitoring of mechanochemical thiocarbamoylation by in situ Raman spectroscopy revealed the formation of aryl N-thiocarbamoylbenzotriazoles, reactive intermediates deemed unisolable in solution. The first-time isolation and structural characterization of these elusive molecules demonstrates the ability of mechanochemistry to access otherwise unobtainable intermediates and offers a new range of masked isothiocyanate reagents.
| Item Type: | Article |
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| Uncontrolled Keywords: | mechanochemistry; reactive intermediates; thiocarbamoylation; thiourea |
| Subjects: | NATURAL SCIENCES NATURAL SCIENCES > Chemistry |
| Divisions: | Division of Organic Chemistry and Biochemistry |
| Depositing User: | Vjekoslav Štrukil |
| Date Deposited: | 08 Dec 2016 15:33 |
| URI: | http://fulir.irb.hr/id/eprint/3178 |
| DOI: | 10.1002/anie.201502026 |
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