The formation of CuCl2-specific metallogels of pyridyloxalamide derivatives in alcohols

Džolić, Zoran; Cametti, Massimo; Milić, Dalibor; Žinić, Mladen (2013) The formation of CuCl2-specific metallogels of pyridyloxalamide derivatives in alcohols. Chemistry - A European Journal, 19 . pp. 5411-5416. ISSN 1521-3765

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Abstract

Isomeric pyridyloxalamide derivatives 1–3, which differed in the position of the nitrogen atom on the pyridyl ring, showed remarkably different gel-forming aptitudes in the presence of CuCl2 salt in alcohols. Whilst derivatives 1 and 3 formed a soluble complex and a solid precipitate, respectively, ligand 2 generated a remarkably metal- and anion-specific metallogel

Item Type:	Article
Uncontrolled Keywords:	metallogels; oxalamides; amino acids; smart materials; Copper complex ; supramolecular chemistry
Subjects:	NATURAL SCIENCES > Chemistry > Organic Chemistry
Divisions:	Division of Organic Chemistry and Biochemistry
Projects:	Project title Project leader Project code Project type Self-Assembly in gels and synthesis of functional hybrid materials (Samo-udruživanje u gelovima i sinteza funkcionalnih hibridnih materijala)- Leo Frkanec 098-0982904-2912 MZOS X-ray structural studies of biological macromolecules (Strukturno istraživanje bioloških makromolekula metodom rentgenske difrakcije)- Dubravka Matković-Čalogović 119-1193079-1084 MZOS
Depositing User:	Zoran Džolić
Date Deposited:	27 Jan 2016 13:28
URI:	http://fulir.irb.hr/id/eprint/2426
DOI:	10.1002/chem.201204082

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