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Synthesis and crystal and molecular structure of trans-[PtCl2(8-dqmp)(2)] - (8-dqmp = diethyl 8-quinolylmethylphosphonate)

Matijašić, Ivanka; Bocelli, Gabrijele; Rizzoli, Corado; Tušek-Božić, Ljerka (1999) Synthesis and crystal and molecular structure of trans-[PtCl2(8-dqmp)(2)] - (8-dqmp = diethyl 8-quinolylmethylphosphonate). Croatica Chemica Acta, 72 (2-3). pp. 531-539. ISSN 0011-1643

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Abstract

The complex trans-[PtCl2(8-dqmp)(2)] - trans-dichloro-bis(diethyl 8-quinolylmethylphosphonate-kappa N)platinum(II) - has been synthesized and the molecular structure has been determined by a crystallographic study. The platinum atom has a slightly distorted trans square-planar configuration with Pt1-N1 = 2.042(4) and Pt1-Cl1 = 2.306(1) Angstrom. The dihedral angle between the Pt coordination plane and the mean plane of the 8-quinolylmethyl moiety is 65.1(1)degrees. The complex reveals a very interesting feature: a very short methylene proton-platinum distance of 2.309(5) Angstrom occupying approximately axial positions around the central metal atom for the hydrogen atom H10B. Refinement was performed by least-squares methods to a final R value of 3.02%.

Item Type: Article
Uncontrolled Keywords: x-ray structure; platinum(II) complex; diethyl 8-quinolylmethylphosphonate; Pt-H interaction; palladium(ii) halide-complexes; transition-metal complexes; h-c interactions; antitumor-activity; schiff-base; ligands; binding; spectroscopy; DNA
Subjects: NATURAL SCIENCES > Chemistry
Divisions: Division of Physical Chemistry
Projects:
Project titleProject leaderProject codeProject type
Novi kemijski spojevi od katalitičkog i biološkog interesaBoris Kamenar119407MZOS
Struktura i bioaktivnost organskih i organometalnih spojevaLjerka Tušek-Božić00980607MZOS
Depositing User: Ljerka Božić
Date Deposited: 26 Nov 2013 12:44
Last Modified: 28 Feb 2014 13:13
URI: http://fulir.irb.hr/id/eprint/1127

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